Regioselective allylgallation of terminal alkynes
PH Lee, Y Heo, D Seomoon, S Kim, K Lee
Index: Lee, Phil Ho; Heo, Yunkiu; Seomoon, Dong; Kim, Sundae; Lee, Kooyeon Chemical Communications, 2005 , # 14 p. 1874 - 1876
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Citation Number: 3
Abstract
The carbometalation of C–C multiple bonds is a very important organic transformation. 1 In particular, the development of allylmetalation of simple unactivated alkynes toward the synthesis of 1,4-dienes is valuable in organic synthesis because of the utility of 1,4-dienes and the limited number of allylmetals available for this purpose. 2 To date various allylmetalations have been reported on the basis of nucleophilic character of allylmetals obtained from allyl halides ...
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