Reaction of tetrachlorogermane with vinylmagnesium chloride

…, IV Sbitneva, AV Kisin, EA Chernyshev

Index: Zhun'; Sbitneva; Kisin; Chernyshev Russian Journal of General Chemistry, 2004 , vol. 74, # 7 p. 1130 - 1131

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Citation Number: 2

Abstract

Glockling et al.[1] reported that the reaction of tetrachlorogermane with vinylmagnesium chloride yielded exclusively the complete vinylation products: tetravinylgermane, hexavinyldigermane, and octavinyltrigermane [1]. We showed that the reaction of a freshly prepared solution of vinylmagnesium chloride in THF (without separation of the precipitate) with a solution of GeCl4 in THF yields a mixture of vinylchlorogermanes of various ...