Metathetical transposition of bis-tert-alkyl ketones. 2. Structural effects on alkyl migration. Existence of linear relation networks

P Bauer, JE Dubois

Index: Bauer,P.; Dubois,J.E. Journal of the American Chemical Society, 1976 , vol. 98, # 22 p. 6999 - 7007

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Citation Number: 6

Abstract

Abstract: Structure-migrating group interactions which are present during 1, 2 migrations of alkyl groups Rm (Rm= Me or Et) have been studied as a function of the influence of a variable environment e,, of the origin carbon C, for a fixed environment Ect of the terminal carbon C,, and vice versa, on the partial rate constant (kPRm) for migration in IV. The constants kpRm were determined from a study, in 96% HzS04, of the metathetical ...