Electron-transfer-induced tautomerization in methylindanones: Electronic control of the tunneling rate for enolization
…, T Bally, T Filipiak, A Marcinek, J Gebicki
Index: Bally, Thomas; Bernhard, Stefan; Matzinger, Stephan; Roulin, Jean-Luc; Narahari Sastry; Truttmann, Leo; Zhu, Zhendong; Marcinek, Andrzej; Adamus, Jan; Kaminski, Rafal; Gebicki, Jerzy; Williams, Ffrancon; Chen, Guo-Fei; Fuelscher, Markus P. Chemistry - A European Journal, 2000 , vol. 6, # 5 p. 858 - 868
Full Text: HTML
Citation Number: 10
Abstract
The radical cations generated from 4-methyl-and 4, 7-dimethylindanone, as well as their deuterated isotopomers, isolated in Argon matrices, were found to undergo enolization to the corresponding enol radical cations at rates that differ by orders of magnitude. It is shown
Related Articles:
The rearrangement of the cubane radical cation in solution
[Schreiner, Peter R.; Wittkopp, Alexander; Gunchenko, Pavel A.; Yaroshinsky, Alexander I.; Peleshanko, Sergey A.; Fokin, Andrey A. Chemistry - A European Journal, 2001 , vol. 7, # 13 p. 2739 - 2744]
[Cassar,L. et al. Journal of the American Chemical Society, 1970 , vol. 92, # 11 p. 3515 - 3518]
Photochemical precursor to cyclobutadiene
[Miller,R.D.; Hedaya,E. Journal of the American Chemical Society, 1969 , vol. 91, p. 5401 - 5402]
3, 4-Diazabenzvalene, the azoalkane precursor to tetrahedrane. Synthesis and reactivity.
[Kaisaki, David A.; Dougherty, Dennis A. Tetrahedron Letters, 1987 , vol. 28, # 44 p. 5263 - 5266]
3, 4-Diazabenzvalene, the azoalkane precursor to tetrahedrane. Synthesis and reactivity.
[Kaisaki, David A.; Dougherty, Dennis A. Tetrahedron Letters, 1987 , vol. 28, # 44 p. 5263 - 5266]