Rates and mechanism of solvolysis of N-phenylcyclosilazoxanes
Z Lasocki, M Witekowa
Index: Lasocki, Zygmunt; Witekowa, Malgorzata Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 49 - 60
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Citation Number: 9
Abstract
Abstract The rates of solvolysis of some N-phenyl-1-aza-3, 5-dioxa-2, 4, 6-tris (dimethylsily) cyclohexanes, substituted in the benzene ring, have been measured spectrophotometrically in methanol containing a small quantity of water. The reaction is subject to general acid catalysis and is inhibited by weak bases. Electron-donating substituents accelerate the solvolysis. The ϱ-constant, derived from the linear relation between the logarithms of the ...
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