Reaction of Dicobalt Octacarbonyl with Some Acetylenic Compounds1

MR Tirpak, CA Hollingsworth…

Index: Tirpak,M.R. et al. Journal of Organic Chemistry, 1960 , vol. 25, p. 687 - 690

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Citation Number: 25

Abstract

The relative rates of reaction of acetylenic acids, alcohols, esters, ethers, halides, and hydrocarbons with dicobalt octacarbonyl have been determined. The differences in the relative reactivities are not great; however, carboxy-, carbomethoxyand methylol-groups appear to enhance the reactivity when attached to the triple bonded carbon. The observed relative reactivities are not correlated with possible electronic effects. A decrease in ...