Conformational and stereoelectronic investigation of chloromethyl methyl sulfide and its sulfinyl and sulfonyl analogs
LC Ducati, MP Freitas, CF Tormena, R Rittner
Index: Ducati, Lucas C.; Freitas, Matheus P.; Tormena, Claudio F.; Rittner, Roberto Journal of Molecular Structure, 2006 , vol. 800, # 1-3 p. 45 - 50
Full Text: HTML
Citation Number: 10
Abstract
The rotational equilibria of some sulfur-containing model compounds were theoretically determined, and a rationalization of the effects responsible for the results obtained is given. Experimental approaches, namely NMR and infrared, were also used to show the gauche (ClCSCH3 fragment) prevalence for these compounds and allowed us to elucidate the orbital interactions involved in such systems. The gauche rotamer of the sulfide is about ...
Related Articles:
Oxidation using distannoxane II. Selective and mild oxidation of sulphides
[Ueno,Y. et al. Tetrahedron Letters, 1977 , # 28 p. 2413 - 2416]
New synthesis of. alpha.-chlorosulfoxides. Reaction of diazo compounds with sulfinyl chlorides
[Venier,C.G. et al. Journal of Organic Chemistry, 1973 , vol. 38, p. 17 - 19]
Acylation Mechanisms of DMSO/[D6] DMSO with Di??tert??butylketene and Its Congeners
[Knorr, Rudolf European Journal of Organic Chemistry, 2011 , # 31 p. 6335 - 6342]