Structure of dibromo (1, 10-phenanthroline) copper (II)

MT Garland, D Grandjean, E Spodine…

Index: Garland, M. T.; Grandjean, D.; Spodine, E.; Atria, A. M.; Manzur, J. Acta Crystallographica, Section C: Crystal Structure Communications, 1988 , vol. 44, p. 1547 - 1549

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Citation Number: 15

Abstract

Abstract.[CuBr2 (CI2HsN2) l~, Mr= 403" 55, mono-clinic, C21, a= 10-005 (2), b= 6.526 (2), c= 10.314 (2) A, fl= 117.52 (1)% V= 597.3 (4) A3, Z= 2, Dx= 2.243 Mg m-3, 2 (No Kct)= 0.71069,/k,#= 8.963 mm-1, F (000)= 386, T= 291 K, R= 0.057 for 746 unique observed reflections. The Cu atom displays a tetragonally elongated (4+ 2) coordination. The four in- plane bonds are to the two N atoms of the 1, 10-phenanthroline molecule and to the cis Br ...