Synthesis of (. alpha.-hydroxyalkyl) trialkylsilanes via a reverse Brook rearrangement
RJ Linderman, A Ghannam
Index: Linderman, Russell J.; Ghannam, Ameen Journal of Organic Chemistry, 1988 , vol. 53, # 12 p. 2878 - 2880
Full Text: HTML
Citation Number: 20
Abstract
Summary: The transmetalation and rearrangement of [a-((trialkylsilyl) oxy) alkyl] trialkylstannanes have been achieved, providing a method for the direct conversion of several aldehydes and cyclohexanone into (a-hydroxyalky1) trialkylsilanes in reasonable yields.
Related Articles:
Synthetic utility and mechanistic studies of the aliphatic reverse Brook rearrangement
[Linderman, Russell J.; Ghannam, Ameen Journal of the American Chemical Society, 1990 , vol. 112, # 6 p. 2392 - 2398]
Synthetic utility and mechanistic studies of the aliphatic reverse Brook rearrangement
[Linderman, Russell J.; Ghannam, Ameen Journal of the American Chemical Society, 1990 , vol. 112, # 6 p. 2392 - 2398]
Nouvelle methode de C-silylation directe de cetones saturees ou α-ethyleniques
[Dunogues,J. et al. Journal of Organometallic Chemistry, 1975 , vol. 87, p. 151 - 167]
[de Jesus,M. et al. Journal of Organometallic Chemistry, 1977 , vol. 132, p. 301 - 320]
Nouvelle methode de C-silylation directe de cetones saturees ou α-ethyleniques
[Dunogues,J. et al. Journal of Organometallic Chemistry, 1975 , vol. 87, p. 151 - 167]