ACS Catalysis

Iron-Catalyzed Amination of Sulfides and Sulfoxides with Azides in Photochemical Continuous Flow Synthesis

H Lebel, H Piras, M Borduy

Index: Wu, Jie; Kozak, Jennifer A.; Simeon, Fritz; Hatton, T. Alan; Jamison, Timothy F. Chemical Science, 2014 , vol. 5, # 3 p. 1227 - 1231

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Citation Number: 4

Abstract

... Using trichloroethoxysulfonyl azide (TcesN 3 ),(15, 16) sulfilimine 1 derived from thioanisole was produced in 90% yield with a residence time (t R ) of 150 min. ... Flow: 0.42 mL/min. Table e 20 mol % of Fe(acac) 3. Table f 2 cycles of 90 min using 2 × 20 mol % of Fe(acac) 3 . ...