Optical stability of carbanions derived from sulphoximides and sulphilimines

R Annunziata, M Cinquini, S Colonna…

Index: Annunziata, Rita; Cinquini, Mauro; Colonna, Stefano; Cozzi, Franco Journal of the Chemical Society, Chemical Communications, 1981 , # 19 p. 1005 - 1006

Full Text: HTML

Citation Number: 0

Abstract

By RITA ANNUNZIATA, MAURO CINQUINI, STEFANO COLONNA, and FRANCO CZZI (Centro CNR e Istituto di Chimica Industriale dell'Universitd, Via C. Golgi 19, 20133 Milano, Italy) ... Summary Pairs of diastereomeric sulphoximides and sulphilimines of known absolute configuration have been converted into the corresponding carbanions, which have a definite optical stability. ... Et Et I I Me -CH -OH Me-CH-SO,-Tol-p p -Tol-S-OMenthyl L 0 ... Me- CH-OTos + Me-CH-S- ...