N??Allylideneamines Derived from Acrolein: Synthesis and Use as Acceptors of Two Nucleophiles

…, Y Matsuda, I Hachiya, M Shimizu

Index: Mizota, Isao; Matsuda, Yuri; Hachiya, Iwao; Shimizu, Makoto European Journal of Organic Chemistry, 2009 , # 24 p. 4073 - 4084

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Abstract

Abstract Two practical methods have been developed for the preparation of N- allylideneamines 1b, c. One involves the isomerization of propargylamines and the other the dehydration of acrolein. N-Allylideneamines 1b, c thus prepared were used as efficient substrates for 1, 4-and 1, 2-double nucleophilic addition reactions.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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