Attempts at Direct Detection of Reactive Species in Selective Excitation of the Contact Charge Transfer Pairs of Hexamethylbenzene and Oxygen.
…, M Tsuchiya, G Furusawa, Y Kuriyama…
Index: Komatsu, Toshiki; Tsuchiya, Masahiro; Furusawa, Gen-ichi; Kuriyama, Yasunao; Sakugari, Hirochika; et al. Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 1 p. 277 - 281
Full Text: HTML
Citation Number: 6
Abstract
Pulsed laser excitation of contact charge transfer pairs of hexamethylbenzene (HMB) and oxygen in methanol-acetonitrile gave no evidence for intermediacy of reactive species such as HMB radical cations and pentamethylbenzyl cations (ArCH 2+), though stationary irradiation of the pair in hydroxylic solvents afforded distinct products arising from the cationic species. The mechanism of reactions was discussed in comparison with 9, 10- ...
Related Articles:
The liquid-phase oxidation of methylbenzenes by the cobalt-copper-bromide system.
[Okada, Toshihiko; Kamiya, Yoshio Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 9 p. 2724 - 2727]
[Mizoguchi, Katsuhisa; Higashihara, Tomoya; Ueda, Mitsuru Macromolecules, 2010 , vol. 43, # 6 p. 2832 - 2839]
The synthesis of polymeric ethers
[Rhoad; Flory Journal of the American Chemical Society, 1950 , vol. 72, p. 2216,2219]
The liquid-phase oxidation of methylbenzenes by the cobalt-copper-bromide system.
[Okada, Toshihiko; Kamiya, Yoshio Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 9 p. 2724 - 2727]
The synthesis of polymeric ethers
[Rhoad; Flory Journal of the American Chemical Society, 1950 , vol. 72, p. 2216,2219]