A short formal total synthesis of (±)-hirsutic acid
G Revol, C Fuchs, SZ Zard
Index: Revol, Guillaume; Fuchs, Christian; Zard, Samir Z. Canadian Journal of Chemistry, 2012 , vol. 90, # 11 p. 927 - 931
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Abstract
A short formal total synthesis of (±)-hirsutic acid is described using a Claisen rearrangement and a radical cascade as the key steps. The radical sequence involves an intermolecular addition of a radical derived from a xanthate followed by a cyclization and transfer of the xanthate group.
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