The Journal of Organic Chemistry

Diphosphine disulfides. III. Influence of structure on the course of phosphinothioic halide-Grignard reactions

NK Patel, HJ Harwood

Index: Patel,N.K.; Harwood,H.J. Journal of Organic Chemistry, 1967 , vol. 32, p. 2999 - 3003

Full Text: HTML

Citation Number: 16

Abstract

Reactions of dimethyl-, diethyl-, or di (n-propy1) phosphinothioic halides with Grignard reagents give trisubstituted phosphine sulfides in high yield. In conflict with results reported by Bogolyubov, it was not possible to obtain diphosphine disulfides from these reactions.