Photochemically induced silylacylations of alkynes with acylsilanes

…, P Becker, H Huang, R Pirwerdjan…

Index: Zhang, Hui-Jun; Becker, Peter; Huang, He; Pirwerdjan, Ramona; Pan, Fang-Fang; Bolm, Carsten Advanced Synthesis and Catalysis, 2012 , vol. 354, # 11-12 p. 2157 - 2161

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Citation Number: 13

Abstract

Abstract Visible light initiates the stereoselective formation of two new bonds, a C [BOND] C and a C [BOND] Si bond, during the addition of acylsilanes to alkynes. At room temperature this photochemically induced transformation can be applied for the preparation of chromone derivatives in a highly atom-economic manner.