Studies on electrochemical and coordination behaviour of phosphiniminocyclotrithiazenes

U Swarnalatha, A Sivaramakrishna…

Index: Swarnalatha; Sivaramakrishna; Venkatachalam; Rao, M.N. Sudheendra; Inoue, Tomonori; Ueda, Tadaharu; Hojo, Masashi Canadian Journal of Chemistry, 2002 , vol. 80, # 11 p. 1428 - 1434

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Citation Number: 8

Abstract

Electrochemical (polarographic, cyclic voltammetric, and coulometric) and coordination behaviour of several symmetrically and unsymmetrically substituted phosphiniminocyclotrithiazenes have been studied. Polarograms of R3PN-S3N3 (R= C6H5, p-ClC6H4, p-H3CC6H4, and (OC4H8N)), Ph2 (OC4H8N) PN-S3N3, and Ph (OC4H8N) 2PN- S3N3 give two cathodic waves. Cyclic voltammograms of Ph3PN-S3N3 (1) and (OC4H8N) ...