The Chemistry of Xylylenes. III. Some Reactions of p-Xylylene that Occur by Free Radical Intermediates2
LA Errede, JM Hoyt
Index: Errede,L.A.; Hoyt,J.M. Journal of the American Chemical Society, 1960 , vol. 82, p. 436 - 439
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Citation Number: 60
Abstract
The high reactivity of p-xylylene is found to be consistent with the calculations of Coulson on the electronic structures of singlet and triplet states of this molecule. p-Xylylcne is diamagnetic at low temperature and yet is extremely reactive toward mono-and diradicals forming a, a'-disubstituted derivatives of p-xylylene and linear copoymers, respectively. The reactivity of p-xylylene is so much greater than that of olefinic monomers that ...
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