A New Method of Acylation and Formylation of Polycyclic Aromatic Hydrocarbons
M Periasamy, MR Reddy, P Bharathi
Index: Periasamy, Mariappan; Rama Reddy, Malladi; Bharathi, Pandi Synthetic Communications, 1999 , vol. 29, # 4 p. 677 - 683
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Abstract
Abstract: Polycyclic aromatic hydrocarbon radical anions, prepared by the addition of sodium to the aromatic hydrocarbon in THF, undergo acylation with carboxylic acid esters and formylation with NN-dialkylformamides. ... Introducing a hnctionality in aromatic hydrocarbons has been of ... CH2(COOH)2, 2 DMF-(CF3S02)20, 3 HF-SbF5/CO 4 reagent systems. ... Alkali metal aromatic radical anions are useful in electron transfer reactions.5 ... They react with a variety of ...
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