Silane surface chemistry of palladium: synthesis of silaethylene, silacyclobutadiene and silabenzene

TM Gentle, EL Muetterties

Index: Gentle, Thomas M.; Muetterties, E. L. Journal of the American Chemical Society, 1983 , vol. 105, # 2 p. 304 - 305

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Citation Number: 15

Abstract

Chemisorption of cycloalkenes on metal surfaces are followed by dehydrogenation processes' that often give chemisorbed C, H, species, eg, cyclohexene-benzene'-, and cyclooctadienecyclmtatetraene.'Because these transformations are facile, we have been exploring the reactions of organosilanes with singlecrystal metal surfaces4 as routes to compounds in which there are Si-C bonds of multiple bond order. With platinum and ...