Journal of the American Chemical Society

Nucleophilic attack on olefins initiated by dimethyl (methylthio) sulfonium fluoroborate (DMTSF). Azasulfenylation

BM Trost, T Shibata

Index: Trost, Barry M.; Shibata, Tohru Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3225 - 3228

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Citation Number: 64

Abstract

X= N, 71 29 98 X= N, 82 18 X= N, 95 5 92.. sa*-a After initial reaction of 1 with the olefin, the organic solvent was evaporated and an aqueous solution of the nucleophile added. DMS= dimethyl sulfide. Full characterization of each product was obtained including IR,'H and sometimes" C NMR, and mass spectra as well as determination of elemental composition by high-resolution mass spectroscopy and/or combustion analysis. e The initial amine was ...