The Journal of Organic Chemistry

Addition of N, N-dichlorocarbamtes to conjugated dienes

FA Daniher, PE Butler

Index: Daniher,F.A.; Butler,P.E. Journal of Organic Chemistry, 1968 , vol. 33, p. 2637 - 2642

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Citation Number: 57

Abstract

Results The addition reactions could be performed in a number of ways. The N, N-dichloro carbamate could be added dropwise to a cooled solution of the diene or vice versa. With gaseous butadiene it was found to be particularly advantageous simply to distil the material, after dilution with nitrogen, into a chilled solution of the N, N-dichloro carbamate. Removal of the solvent afforded near quantitative yields of monoadduct. The crude products were ...