Tetrahedron letters

Normal, abnormal and pseudo-abnormal reaction pathways for the imine-peroxyacid reaction

…, PB Coulter, ND Sharma, WB Jennings, VE Wilson

Index: Boyd, Derek R.; Coulter, Peter B.; Sharma, Narain D.; Jennings, Brian W.; Wilson, Valerie E. Tetrahedron Letters, 1985 , vol. 26, # 13 p. 1673 - 1676

Full Text: HTML

Citation Number: 15

Abstract

Abstract Steric and mesomeric effects have a marked influence upon the formation of oxaziridine (normal pathway) or nitrone (abnormal pathway) products from the imine- peroxyacid reaction; nmr studies of the thermal isomerization of oxaziridines to nitrones provide evidence of a pseudo-abnormal oxidation pathway.