Rational synthesis of meso-substituted porphyrins bearing one nitrogen heterocyclic group
D Gryko, JS Lindsey
Index: Gryko, Dorota; Lindsey, Jonathan S. Journal of Organic Chemistry, 2000 , vol. 65, # 7 p. 2249 - 2252
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Citation Number: 98
Abstract
Tailoring the perimeter of the porphyrin macrocycle with diverse substituents in defined patterns is essential for studies in biomimetic and materials chemistry. 1, 2 Small nitrogen heterocycles are substituents of particular interest, 3 providing sites for metal coordination, hydrogenbonding, alkylation (water solubilization), and modulation of the electronic properties of the porphyrin. Indeed, pyridine substituents have yielded a broad array of ...
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