Stereoselective synthesis of a C-glycosylic compound (a “methyl C-glycoside”) through a regioselective free-radical ring-opening reaction. A single-crystal X-ray …

B Shanmugasundaram, B Varghese…

Index: Carbohydrate Research, , vol. 337, # 17 p. 1523 - 1527

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Abstract

... 3 An ongoing research project in this area in our laboratory is the development ... 6-tri-O-acetyl-d- glucal, have found widespread use as carbohydrate synthons. ... Several methodologies have been employed in the last decade for stereocontrolled cyclopropanation in carbohydrates. ...