Preparation of polyfunctional diorganomercurials and their transmetallation to diorganozincs. Applications to the preparation of optically active secon
…, D Rajagopal, CE Tucker, P Knochel
Index: Rozema, Michael J.; Rajagopal, Duddu; Tucker, Charles E.; Knochel, Paul Journal of Organometallic Chemistry, 1992 , vol. 438, # 1.2 p. 11 - 27
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Citation Number: 28
Abstract
Abstract Two new methods of preparation of functionalized diorganomercurials have been developed. The first method involves a substitution reaction of (ICH 2 Their transmetallation with zinc dust (toluene, 80 C, 3–5 h) affords dialkylzincs which add enantioselectively to aldehydes in the presence of a ca
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