Preparation and Reactivities of (. ETA. 3-1-and 2-Trimethylsiloxyallyl) Fe (CO) 2NO Complexes. Intermediates Functioning as Equivalents of. BETA.-and. ALPHA.-Acyl …
K Itoh, S Nakanishi, Y Otsuji
Index: Itoh, Keiji; Nakanishi, Saburo; Otsuji, Yoshio Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 10 p. 2965 - 2977
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Citation Number: 21
Abstract
(η 3-1-and 2-Trimethylsiloxyallyl) Fe (CO) 2 NO complexes were prepared by the reaction of the corresponding siloxyallylic halides with Bu 4 N [Fe (CO) 3 NO]. These complexes reacted with both of carbon nucleophiles and carbon electrophiles preferentially at the less hindered sites of the allylic ligands. In these reactions,(η 3-1-trimethylsiloxyallyl) Fe (CO) 2 NO complexes served as synthetically equivalent synthons for both of β-acyl carbocations ...
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