Micellar catalysis of organic reactions. Part 35. Kinetic determination of the critical micelle concentration of cationic micelles in the presence of additives

TJ Broxton, JR Christie, AJ Dole

Index: Broxton, Trevor J.; Christie, John R.; Dole, Anthony J. Journal of Physical Organic Chemistry, 1994 , vol. 7, # 8 p. 437 - 441

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Citation Number: 35

Abstract

Abstract The critical micelle concentration of solutions of cetyltrimethylammonium bromide and of tetradecyltrimethylammonium bromides were determined by a kinetic method. This involved the determination of the rates of the hydroxydehalogenation of some activated aromatic substrates over a wide range of detergent concentrations. Measurements were made in solutions containing significant quantities of added hydroxyl ion and substrates ...