Chemistry of trivalent iodine—III: The action of iodobenzene dichloride on primary alcohols and aldehydes11NCL Communication No. 2763.
TP Mohandas, AS Mamman, PM Nair
Index: Mohandas, T. P.; Mamman, Ajit, S.; Nair, P. Madhavan Tetrahedron, 1983 , vol. 39, # 7 p. 1187 - 1188
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Abstract
Iodobenzene dichloride reacts with saturated primary alcohols at room temperature in the presence of pyridine to give esters and acid chlorides. With the corresponding aldehydes, only the latter type of product is obtained. While pivaldehyde reacts normally, benzaldehyde is unaffected by the reagent under the same conditions. Presence of moisture results in formation of acids. It is suggested that reactions of both types of substrates involve base ...
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