The mechanism of oxidation of acetals by ozone. I. Stoichiometry, order of the reaction, solvent effects, and substituent effects

…, SE Thomas, Y Nadeau, S Fliszar…

Index: Taillefer, Roland J.; Thomas, Shirley E.; Nadeau, Yves; Fliszar, S.; Henry, Herve Canadian Journal of Chemistry, 1980 , vol. 58, p. 1138 - 1143

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Citation Number: 27

Abstract

A systematic investigation of the reaction between ozone and acetals to form acetal hydrotrioxides A has been undertaken. The stoichiometry of the reaction has been shown to be 1: 1 in each reactant and the order of the reaction was also one in each reactant. Substituent effects measured in a variety of systems and under several conditions of temperature and solvent were found to be small (ρ=-1.10 to-1.58). Solvent polarity was ...