Chemical physics letters

An HT FFR kinetics study of the reaction between AlCl and CO 2 from 1175 to 1775 K

DF Rogowski, A Fontijn

Index: Rogowski, Donald F.; Fontijn, Arthur Chemical Physics Letters, 1986 , vol. 132, p. 413 - 416

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Citation Number: 10

Abstract

Abstract Rate coefficients for the reaction A1C1+ CO 2→ OAlCl+ CO have been measured in a high-temperature fast-flow reactor (HT FFR). These fit the expression k (T)= 2.5× 10− 12 exp (− 7550 K/T) cm 3 molecule− 1 s− 1. The existence of a large energy barrier for this exothermic reaction is in agreement with that suggested for the OAlCl channel of the AlCl+ O 2 reaction. The presence of such barriers is in sharp contrast to the AlO reactions with CO ...