Novel Pathway to Synthesize Unsymmetrical 2, 3, 9, 10, 16, 17, 23-heptakis (alkoxyl)-24-mono (dimethylaminoalkoxyl) phthalocyanines
Z Bai, Y Gao, P Zhu, Y Bian, J Jiang
Index: Bai, Zhaopin; Gao, Yingning; Zhu, Peihua; Bian, Yongzhong; Jiang, Jianzhuang Inorganic Chemistry, 2010 , vol. 49, # 19 p. 9005 - 9011
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Citation Number: 13
Abstract
A new pathway by means of transetherification during the cyclic tetramerization of 4, 5-di (alkoxyl) phthalonitrile has been developed for the synthesis of a series of novel unsymmetrical 2, 3, 9, 10, 16, 17, 23-heptakis (alkoxyl)-24-mono (dimethylaminoalkoxyl) phthalocyanines M {Pc (OR) 7 (OR′)}(M= 2H, Cu)[R= C4H9, C5H11, C8H17; R′= C2H4, CH (CH3) CH2].
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