Specifically deuteriated bicyclo [3.2. 0] hepta-2, 6-dienes
JE Baldwin, KD Belfield
Index: Baldwin, John E.; Belfield, Kevin D. Journal of Organic Chemistry, 1987 , vol. 52, # 21 p. 4772 - 4776
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Citation Number: 14
Abstract
Hofmann degradation of the trimethylammonium hydroxide derived from 9 by way of the oxime and the 6-amino bicyclic olefin achieved the first synthesis of 1, in very low yield. g Reduction of ketone 9 gives predominantly the endo alcohol; mesylate, tosylate, and methyl xanthate derivatives of the alcohol react solvolytically or thermally to give mostly cy~ lohepta- 1, 3, 5-triene.~~~~
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