Reactivity of diacyloxyiodobenzenes toward trivalent phosphorus nucleophiles
S Makowiec, J Rachon
Index: Makowiec, Slawomir; Rachon, Janusz Heteroatom Chemistry, 2003 , vol. 14, # 4 p. 352 - 359
Full Text: HTML
Citation Number: 5
Abstract
Abstract The reaction of diacyloxyiodobenzenes and tetravalent phosphorus nucleophiles was investigated. It was established that both H-phosphonates and secondary phosphine oxides react with diacetoxyiodobenzene in alcohols in the presence of sodium alcoholates yielding trialkyl phosphates and alkyl phosphinates respectively. For this transformation reactive intermediate 6 is proposed. In contrast to this, the treatment of ...
Related Articles:
Electrocatalytic eco-efficient functionalization of white phosphorus
[Budnikova, Yulia H.; Yakhvarov, Dmitry G.; Sinyashin, Oleg G. Journal of Organometallic Chemistry, 2005 , vol. 690, # 10 p. 2416 - 2425]
Reactions of group V metal compounds with sulfur trioxide.
[Ando, Fumio; Koketsu, Jugo; Ishii, Yoshio Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 11 p. 3495 - 3499]
[Malet; Moreno-Manas; Pleixats Synthetic Communications, 1992 , vol. 22, # 15 p. 2219 - 2228]
Reactions of group V metal compounds with sulfur trioxide.
[Ando, Fumio; Koketsu, Jugo; Ishii, Yoshio Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 11 p. 3495 - 3499]
[Koenig, T.; Habicher, W. D.; Schwetlick, K. Journal fuer Praktische Chemie (Leipzig), 1989 , vol. 331, # 6 p. 913 - 922]