FeCl2??Promoted Cleavage of the Unactivated C C Bond of Alkylarenes and Polystyrene: Direct Synthesis of Arylamines

C Qin, T Shen, C Tang, N Jiao

Index: Qin, Chong; Shen, Tao; Tang, Conghui; Jiao, Ning Angewandte Chemie - International Edition, 2012 , vol. 51, # 28 p. 6971 - 6975

Full Text: HTML

Citation Number: 32

Abstract

Selective metal-promoted CÀC bond cleavage under mild reaction conditions presents one of the most challenging and attractive processes [1] because: 1) it enables the straightforward utilization of hydrocarbons in organic synthesis; 2) polymers, which are not biodegradable and produce a large amount of environmental pollution, may be degraded and reused by chemical CÀC bond cleavage; 3) the liquefaction of biomass and coal ...

Related Articles:

Bis (amidate) bis (amido) titanium complex: a regioselective intermolecular alkyne hydroamination catalyst

[Yim, Jacky C.-H.; Bexrud, Jason A.; Ayinla, Rashidat O.; Leitch, David C.; Schafer, Laurel L. Journal of Organic Chemistry, 2014 , vol. 79, # 5 p. 2015 - 2028]

One-pot reductive mono-N-alkylation of aromatic nitro compounds using nitriles as alkylating reagents

[Neogi, Subhasish; Naskar, Dinabandhu Synthetic Communications, 2011 , vol. 41, # 13 p. 1901 - 1915]

Alkylation of amines using trivalent bismuth derivatives

[Barton, Derek H. R.; Ozbalik, Nubar; Ramesh, Manian Tetrahedron Letters, 1988 , vol. 29, # 8 p. 857 - 860]

Iminomalonate as a Convenient Electrophilic Amination Reagent for Grignard Reagents.

[Niwa, Yasuki; Takayama, Kazuki; Shimizu, Makoto Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 8 p. 1819 - 1825]

Electrophilic amination with iminomalonate

[Niwa, Yasuki; Takayama, Kazuki; Shimizu, Makoto Tetrahedron Letters, 2001 , vol. 42, # 32 p. 5473 - 5476]

More Articles...