Addition reactions of haloolefins. XII. The reaction of trifluorochloroethylene with monofluorochloromethanes in the presence of aluminium chloride

O Paleta, A Pošta, K Tesařík

Index: Paleta,O. et al. Collection of Czechoslovak Chemical Communications, 1971 , vol. 36, p. 2257 - 2266

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Citation Number: 4

Abstract

The reaction of trifluorochloroethylene with f1uorotrichloromethane in the presence of aluminium chloride afforded a mixture of five isomeres of tetrafluorotetrachloropropane among which 1, 1, 1, 2-tetrafluoro-(Ia) and 1, 1, 2, 2-tetrafluorotetrachloropropane (Ib) prevail, their relative amounts in the mixture being 49 and 36%. An analogous reaction of trifluorochloroethylene with f1uorodichloromethane gave a mixture of five isomers of ...