Asian Journal of Chemistry

Synthesis and Enantiomer Separation of 5-(1-(3, 5-Dinitrobenzoylamino) pent-4-enyl) acenaphthene

C Xu, W Luo, L Li, S Yao, H Song

Index: Xu, Chao; Luo, Wen-Feng; Li, Li-Jun; Yao, Shun; Song, Hang Asian Journal of Chemistry, 2010 , vol. 22, # 5 p. 3923 - 3928

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Abstract

Abstract A new racemic (±) 5-(1-(3, 5-dinitrobenzoylamino) pent-4-enyl) acenaphthene was synthesized and successfully separated into enantiomers on chiral HPLC. The synthetic approach to the 5-(1-(3, 5-dinitrobenzoylamino) pent-4-enyl) acenaphthene is via Friedel- Crafts acylation reaction to the acenaphthyl ring, α-H substituent reaction to the ketone, deoxidization reaction to the ketone and amidation reaction to the amidocyanogen. The ...