A convenient preparation of vinyl ketones

AE Vanstone, JS Whitehurst

Index: Vanstone,A.E.; Whitehurst,J.S. Journal of the Chemical Society [Section] C: Organic, 1966 , p. 1972 - 1973

Full Text: HTML

Citation Number: 2

Abstract

By AE Vanstone and J. S. Whitehurst Vinyl ketones can be prepared by oxidation of the corresponding allyl alcohols with chromic acid in a two phase ether-water system. ... THE most usual method for the preparation of vinyl ketones is the Lewis acid-catalysed reaction of acid chlorides with ethy1ene.l It is, however, tedious and often gives poor yields., We were attracted to the possibility of using chromic acid oxidation of the allyl alcohols because the original procedures 3 ...

Related Articles:

Biosynthesis of tetronasin: Part 6. Preparation of structural analogues of the diketide and triketide biosynthetic precursors to tetronasin

[Less, Simon L.; Handa, Sandeep; Millburn, Karen; Leadlay, Peter F.; Dutton, Christopher J.; Staunton, James Tetrahedron Letters, 1996 , vol. 37, # 20 p. 3515 - 3518]

Reactions of the carbanion of chloromethyl methyl sulfone with aldehydes and ketones

[Makosza, Mieczyslaw; Urbanska, Natalia; Chesnokov, Alexey A. Tetrahedron Letters, 2003 , vol. 44, # 7 p. 1473 - 1475]

Synthesis of 3-oxooxa-and 3-oxoazacycloalk-4-enes by ring-closing metathesis. Application to the synthesis of an inhibitor of cathepsin K

[Taillier, Catherine; Hameury, Thomas; Bellosta, Veronique; Cossy, Janine Tetrahedron, 2007 , vol. 63, # 21 p. 4472 - 4490]

The Epoxidation of Some Allylic Alcohols1, 2

[Sassiver,M.L.; English,J. Journal of the American Chemical Society, 1960 , vol. 82, p. 4891 - 4895]

More Articles...