449. Reactions of unsaturated compounds. Part XIV. The oxidation of 2: 2: 4: 6: 6-pentamethylhept-3-ene

MA Davis, WJ Hickinbottom

Index: Davis; Hickinbottom Journal of the Chemical Society, 1957 , p. 1998 Journal of the Chemical Society, 1958 , p. 2205,2207

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Citation Number: 11

Abstract

Ho/cr\ o-oxide in acetic anhydride, yet are oxidised by aqueous sulphuric-chromic acid faster than the epoxide is hydrated by aqueous sulphuric acid of the same strength. It is these observations which have confirmed the view that the epoxide is not the true intermediate in the oxidation, but that in suitable circumstances it can be derived from some addition complex of the olefin and the oxidising agent. In an earlier paper, it was suggested that ...