Chemical Communications

A remarkable solvent effect toward the Pd/C-catalyzed cleavage of silyl ethers

H Sajiki, T Ikawa, K Hattori, K Hirota

Index: Sajiki, Hironao; Ikawa, Takashi; Hattori, Kazuyuki; Hirota, Kosaku Chemical Communications, 2003 , # 5 p. 654 - 655

Full Text: HTML

Citation Number: 24

Abstract

The protection of alcohols as their silyl ethers has been recognized as a most useful protective method. Since the introduction of the tert-butyldimethylsilyl (TBDMS) protective group in 1972, 1 alcohols and phenols have been quite commonly protected as their TBDMS ethers. 2 TBDMS ethers have the virtue of being very stable to a variety of organic reactions. 2 In general, TBDMS ethers have been believed to be also stable under hydrogenation ...

Related Articles:

An efficient synthesis of silyl ethers of primary alcohols, secondary alcohols, phenols and oximes with a hydrosilane using InBr 3 as a catalyst

[Sridhar, Madabhushi; Raveendra, Jillella; China Ramanaiah, Beeram; Narsaiah, Chinthala Tetrahedron Letters, 2011 , vol. 52, # 45 p. 5980 - 5982]

Highly Efficient and Chemoselective Ruthenium??Catalyzed Hydrosilylation of Aldehydes

[Do, Youngshil; Han, Junghoon; Rhee, Young Ho; Park, Jaiwook Advanced Synthesis and Catalysis, 2011 , vol. 353, # 18 p. 3363 - 3366]

Rhodium (II) perfluorobutyrate catalyzed silane alcoholysis. A highly selective route to silyl ethers

[Doyle, Michael P.; High, Kenneth G.; Bagheri, Vahid; Pieters, Roland J.; Lewis, Patricia J.; Pearson, Matthew M. Journal of Organic Chemistry, 1990 , vol. 55, # 25 p. 6082 - 6086]

Rhodium-Catalyzed, Efficient Deutero-and Tritiosilylation of Carbonyl Compounds from Hydrosilanes and Deuterium or Tritium

[Rubio, Miguel; Campos, Jesuus; Carmona, Ernesto Organic Letters, 2011 , vol. 13, # 19 p. 5236 - 5239]

Selective reduction of carboxylic acids to aldehydes catalyzed by b (c6f5) 3

[Bezier, David; Park, Sehoon; Brookhart, Maurice Organic Letters, 2013 , vol. 15, # 3 p. 496 - 499]

More Articles...