Crystal structures of copper (II) complexes of 2-formylpyridine substituted thiosemicarbazones; the first example of a coordinated thiosemicarbazone with a thiol …

DX West, JK Swearingen, TJ Romack, IS Billeh…

Index: West; Swearingen; Romack; Billeh; Jasinski; Li; Staples Journal of Molecular Structure, 2001 , vol. 570, # 1-3 p. 129 - 136

Full Text: HTML

Citation Number: 1

Abstract

The crystal structures of two 5-coordinate copper (II) complexes containing neutral, tridentate 2-formylpyridine N (4)-substituted thiosemicarbazones have been determined. 2- Formylpyridine N (4)-cyclohexylthiosemicarbazone, HFo4CHex coordinates via the pyridine nitrogen, imine nitrogen and thione sulfur with two chloro ligands to produce [Cu (HFo4CHex) Cl2]. Similarly, 2-formylpyridine 3-(4-methylpiperazine) thiosemicarbazone, ...

Related Articles:

More Articles...