Self-Assembly, Crystal Structure, and Magnetic Properties of a Phenoxo-Bridged Tetranuclear CuII Complex of the[2× 2] Grid Type

…, G Baum, D Fenske, O Waldmann, P Müller

Index: Rojo, Javier; Lehn, Jean-Marie; Baum, Gerhard; Fenske, Dieter; Waldmann, Oliver; Mueller, Paul European Journal of Inorganic Chemistry, 1999 , # 3 p. 517 - 522

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Citation Number: 44

Abstract

The ditopic ligand 3 has been synthesized. In its crystallography. Magnetic studies of complex 1 indicate a very weak antiferromagnetic coupling between the deprotonated form, it reacts with copper (II) ions to form a tetranuclear complex 1 of the [2× 2] CuII 4 grid type, the phenoxo-bridged CuII ions. structure of which has been confirmed by X-ray