Thermochemical parameters of dialkyldithiocarbamate chelates of indium (III)
AG Souza, MM Oliveira, AD Gondim, PO Dunstan…
Index: Souza, Antonio Gouveia; Oliveira, Marcelo Moizinho; Gondim, Amanda Duarte; Dunstan, Pedro Oliver; Melo, Dulce Maria De A. Thermochimica Acta, 2000 , vol. 344, # 1-2 p. 29 - 35
Full Text: HTML
Citation Number: 0
Abstract
A series of dialkyldithiocarbamate chelates of indium (III) of the general formula In (S2CNR2) 3,(R= C2H5, n-C3H7, i-C3H7, n-C4H9 and i-C4H9), were prepared from the reaction of hydrochloric acid solution of metallic indium and the corresponding dialkylammonium salt of the ligand at pH= 3–4, giving yields better than 78%. The standard molar enthalpies of formation of crystalline dialkyldithiocarbamate chelates of In (III), were determined through ...