The elimination of carbon monoxide from acid derivatives. Part III. Planar carbonium ions as necessary intermediates
DG Pratt, E Rothstein
Index: Pratt,D.G.; Rothstein,E. Journal of the Chemical Society [Section] C: Organic, 1968 , p. 2548 - 2554
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Citation Number: 4
Abstract
Elimination of carbon monoxide from acid chlorides by the Friedel-Crafts reaction is precluded if the resulting carbonium ions are restricted to non-planar geometry by bicyclic or other structures with a rigid molecular framework. In such cases the normal ketones are obtained.
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