3, 4-Ethylenedioxythiophene and 3, 4-Ethylenedioxyselenophene: Synthesis and Reactivity of Cα− Si Bond
S Das, PK Dutta, S Panda, SS Zade
Index: Das, Soumyajit; Dutta, Pradip Kumar; Panda, Snigdha; Zade, Sanjio S. Journal of Organic Chemistry, 2010 , vol. 75, # 14 p. 4868 - 4871
Full Text: HTML
Citation Number: 17
Abstract
A synthetic approach to synthesize EDOT and EDOS from a common precursor 5 is reported. The method involves zirconocene dichloride mediated reaction of a common diyne 5 followed by treatment with disulfur dichloride (S2Cl2) and in situ prepared selenium dichloride (SeCl2). The higher lability of α-trimethylsilyl group in EDOS compared to EDOT is explained using DFT calculations.
Related Articles:
[Chen, Shuai; Lu, Baoyang; Duan, Xuemin; Xu, Jingkun Journal of Polymer Science, Part A: Polymer Chemistry, 2012 , vol. 50, # 10 p. 1967 - 1978]
[Journal of Materials Chemistry, , vol. 15, # 45 p. 4783 - 4792]
Synthesis of 3, 4-Ethylenedioxythiophene (EDOT) from (Z)-But-2-ene-1, 4-diol or But-2-yne-1, 4-diol
[Heterocycles, , vol. 82, # 1 p. 449 - 460]
Synthesis of 3, 4-Ethylenedioxythiophene (EDOT) from (Z)-But-2-ene-1, 4-diol or But-2-yne-1, 4-diol
[Heterocycles, , vol. 82, # 1 p. 449 - 460]
Synthesis of 3, 4-Ethylenedioxythiophene (EDOT) from (Z)-But-2-ene-1, 4-diol or But-2-yne-1, 4-diol
[Heterocycles, , vol. 82, # 1 p. 449 - 460]