Ligandless Copper??Catalyzed Coupling of Heteroaryl Bromides with Gaseous Ammonia
S Fantasia, J Windisch…
Index: Fantasia, Serena; Windisch, Johannes; Scalone, Michelangelo Advanced Synthesis and Catalysis, 2013 , vol. 355, # 4 p. 627 - 631
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Citation Number: 8
Abstract
Abstract A range of different N-and S-containing heterocyclic bromides can be efficiently coupled with gaseous ammonia in the presence of copper (II) acetylacetonate [Cu (acac) 2] as catalyst and in the absence of additional ligands. Unstable aminothiophenes and aminobenzothiophenes can be further reacted in situ to afford functionalized derivatives.
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