Journal of the Chemical Society C: Organic

Reactive intermediates. Part IV. The amination of naphtho [1, 8-de]-triazine

CW Rees, RC Storr

Index: Rees,C.W.; Storr,R.C. Journal of the Chemical Society [Section] C: Organic, 1969 , p. 756 - 760

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Citation Number: 29

Abstract

Amination of naphtho [1, 8-] triazine with aqueous hydroxylamine--sulphonic acid gives 1- aminonaphtho-[1, 8-] triazine and 1-amino-8-azidonaphthalene. Amination with ethereal chloramine gives 1-and 2-aminonaphthotriazines and the latter was shown to rearrange to the amino-azide under the conditions of the hydroxylamine