Kinetics and dynamics in the photodissociation of the allyl radical

…, T Gilbert, I Fischer, P Chen

Index: Deyerl, Hans-Juergen; Gilbert, Thomas; Fischer, Ingo; Chen, Peter Journal of Chemical Physics, 1997 , vol. 107, # 8 p. 3329 - 3332

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Citation Number: 41

Abstract

Abstract The direct observation of the products, kinetics and translational energy release from the photodissociation of the allyl radical, C 3 H 5, upon excitation in the near-uv is reported. A statistical analysis of the data shows that they are in agreement with allene formation being the dominant H-loss reaction channel.

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