Photoinduced electron transfer from dialkyl nitroxides to halogenated solvents

J Chateauneuf, J Lusztyk, KU Ingold

Index: Chateauneuf, J.; Lusztyk, J.; Ingold, K. U. Journal of Organic Chemistry, 1990 , vol. 55, # 3 p. 1061 - 1065

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Citation Number: 26

Abstract

Conclusions 1. The analysis of the reaction products of the thermolyses of some substituted tetraoxanes in benzene solution and the corresponding activation parameters for these unimolecular reactions support a general homolytic stepwise mechanism, rather than a concerted process. 2. A genuine" isokinetic relationship" is observed for the unimolecular homolyses of the acetophenone, benzyl ketone, benzophenone, cyclohexanone and ...