Platinum (IV)-Assisted [2+ 3] cycloaddition of nitrones to coordinated organonitriles. Synthesis of Δ4-1, 2, 4-oxadiazolines

…, AJL Pombeiro, VY Kukushkin

Index: Wagner, Gabriele; Pombeiro, Armando J. L.; Kukushkin, Vadim Yu. Journal of the American Chemical Society, 2000 , vol. 122, # 13 p. 3106 - 3111

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Citation Number: 107

Abstract

[2+ 3] cycloaddition between acetonitrile ligands in the platinum (IV) complex [PtCl4 (MeCN) 2] and the nitrones-O+ N (R3) C (R1)(R2)[R1= H, R2= Ph, o-C6H4OH, p-C6H4Me, p- C6H4OMe, p-C6H4NO2, p-C6H4NMe2, p-C6H4NMe2⊙ HCl, R3= Me; R1= H, R2= Ph, t ...